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Molecules, Transport and Health

Lipids

Pearson Edexcel International A Level Biology


Triglycerides

  • A triglyceride is one glycerol molecule and three fatty acid molecules.
  • They join by a condensation reaction, catalysed by enzymes, and three molecules of water are formed.
  • Glycerol and the fatty acids are joined by ester bonds: three in each triglyceride.
  • A fatty acid is RCOOH: R is the hydrocarbon chain.
HHCHCHCHOHHOCOROHHOCOROHHOCORHHCHCHCHOCOROCOROCOR+ 3H2Oglycerolthree fatty acidstriglycerideester bond
One glycerol and three fatty acids condense to a triglyceride with three ester bonds, forming three molecules of water; the dashed outlines mark the atoms removed.

Saturated and unsaturated fatty acids

Fatty acidBonds between carbonsHydrogens
SaturatedDo not contain carbon-carbon double bondsMore for the same number of carbons
UnsaturatedContain carbon-carbon double bondsFewer hydrogens for the same number of carbons
  • Both contain carbon and hydrogen and oxygen and contain covalent bonds only. Never write fatty acids both contain ester bonds.
  • Unsaturated fatty acids are kinked; saturated fatty acids are straight.
  • Drawing an unsaturated fatty acid: at least one carbon-carbon double bond drawn in the chain, with one H removed from each carbon of the double bond. C1 is the carboxyl carbon: never place a double bond between C1 and C2.
The C=O in every fatty acid

Every fatty acid has a C=O double bond in its carboxyl group, so a saturated fatty acid has no carbon-carbon double bonds. Never write saturated fatty acids have no double bonds.

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