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States of Matter

States of Matter and Diffusion

Cambridge IGCSE Chemistry


The three states

solidliquidgas
The particles in a solid, a liquid and a gas.
StateSeparationArrangementMotion
solidtouchingregularvibrate about fixed positions
liquidtouchingrandomrandom, moving past each other
gasfar apartrandomrandom, moving quickly in all directions

A solid has a fixed shape and a fixed volume; a liquid has a fixed volume and takes the shape of its container; a gas fills its container.

The state at a given temperature

TemperatureState
below the melting pointsolid
between the melting point and the boiling pointliquid
above the boiling pointgas
  • For a liquid, compare the temperature with both points in one answer: the melting point is below the temperature and the boiling point is above it.
  • For a gas: the temperature is above the boiling point.
  • With negative temperatures, the larger the number after the minus sign, the lower the temperature.

Changes of state

ChangeFromTo
meltingsolidliquid
freezingliquidsolid
boilingliquidgas
evaporationliquidgas
condensationgasliquid

Boiling happens at a specific temperature and throughout the liquid; evaporation happens over a range of temperatures and is a surface process.

liquid coolsfreezing at the melting pointsolid coolstimetemperature
A cooling curve for a liquid that freezes.

A cooling curve falls, is a horizontal line at the melting point while the liquid freezes, then falls again. Each horizontal section is a change of state.

Diffusion

  • In diffusion, particles move from an area of high to low concentration because the particles move randomly.
  • A smell spreads across a room by evaporation of the liquid, then diffusion of its particles.
  • A gas with a lower relative molecular mass diffuses faster.
  • Of several gases, the one with the lowest relative molecular mass diffuses fastest.

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